Verified Answer :
Given:
20.0 ml of glacial acetic acid
1.70 L with water
density of the glacial acetic acid is 1.05 g/ml ; Ka = 1.8 x 10⁻⁵
1) find out how many grams of HC2H3O2 is in this glacial matter. It says here it has a density of 1.05g/mL.
So we find the grams from that => 1.05 g/mL * (20.0 mL) = 21 grams of HC2H3O2.
Convert this to moles => 21 grams (1 mol / 60 g) = 0.35 mol HC2H3O2
We then get the Ka formula from that equation so it is
Ka = [H3O+] [C2H3O2] / [HC2H3O2] (Remember H2O has an activity of 1 so we exclude it)
We know the concentration of HC2H3O2 because we have moles of HC2H3O2
Finding concentration of HC2H3O2 => 0.35 mol HC2H3O2/1.70 L = 0.20588 M - initial concentration
1.8 x 10⁻⁵ = (x) (x) / (0.20588 M - x)
1.8 X 10⁻⁵ (0.20588 M) = x²
3.70584⁻ x 10⁻⁶ = x²
x = 1.9251 x 10⁻³
pH = -log (H₃O⁺) = - log (1.9251 x 10⁻³) = -(-2.7156) = 2.7156
pH of the resulting solution is 2.7156
The pH of the resulting solution is 2.72
Data;
- volume of acid = 20mL
- density of acid = 1.05 g/ml
- mass = 1.05 20 = 21g
pH of a solution
The number of moles of acetic acid is
\(n = 21/60 = 0.333 moles\)
The concentration of acetic acid in 1.7L is
\(c = \frac{0.333}{1.7} = 0.196M\)
The equation for dissociation is
\(CH_3COOH + H_2O \to CH_3COO^- +H_3O^+\)
The Ka of this reaction is
\(K_a = \frac{[CH_3COO^-][H_3O^+}{[CH_3COOH}\)
The Ka of acetic acid = 1.810^-5
\(1.8*10^-^5 = \frac{x*x}{0.196} \\x = 0.187*10^-^2M\\\)
The concentration of hydrogen ion is
\([H^+] = 1.87*10^-^3M\)
The pH of this solution is
\(pH = -log[H^+]\\pH = -log(1.87*10^-^3)\\pH = 2.72\)
The pH of the resulting solution is 2.72
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