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A calorimeter contains 500 g of water at 25°C. You place a hand warmer containing 100 g of liquid sodium acetate (NaAC) inside the calorimeter. When the sodium acetate finishes crystallizing, the temperature of the water inside the calorimeter is 32.2°C. The specific heat of water is

4.18 J/g-°C. What is the enthalpy of fusion (ΔHf) of the sodium acetate? Show your work.

Verified Answer :

The heat absorbed by the water is
Q = 500 (4.18) (32.2 - 25)
Q = 15048 J

The enthalpy of fusion of the sodium acetate is:
ΔHf = Q / m
ΔHf = 15048 / 100
ΔHf = 150.48 J/g

Answer:The enthalpy of fusion \((ΔH_f)\) of the sodium acetate is 12.344 kJ/mol.

Explanation:

Heat absorbed by the water: Q

Change in temperature of water,\(\Delta T=32.2^oC-25^oC=7.2^oC\)

Specific heat of water = 4.18 J/g°C

Mass of water = m= 500 g

\(Q=500 g\times 4.18 J/g ^oC\times 7.2^oC=15,048 J\)

\(\Delta H_f\) is the heat energy required to melt the one mole of substance.

When 200 g of sodium acetate crystallizes it gave 15,048 Joules of heat which was absorbed by the water in calorimeter.

\(NaAC(l)\rightarrow NaAC(s),\Delta H_f=?\)

Moles of NaAC=\(\frac{100 g}{82.03 g.mol}=1.2190 mol\)

\(\Delta H_f=\frac{15,048 J}{1.2190 mol}=12,344 J/mol=12.344 kJ/mol\)

The enthalpy of fusion \((ΔH_f)\) of the sodium acetate is 12.344 kJ/mol.