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Verified Answer :

1.00 x 10-14 mol2 dm-6 at room temperature. In fact, this is its value at a bit less than 25°C.

Answer: The value of \(K_w \text{ at } 25^oC \text{ is }1\times 10^{-14}\)

Explanation:

\(H_2O\rightleftharpoons H^++OH^-\)

\(K_{eq}=\frac{[H^+]\times [OH^-]}{[H_2O]}\)

\(K_{eq}\times[H_2O]=K_w=[H^+]\times [OH^-]\)

Since, water is neutral with value pH of 7 at \(25^oC\). So, the concentration of \([H^+] and [OH^-]\) will be equal.

\(pH=7=-log[H^+]=\) so, the value of \(H^+\) will be

\([H^+]=1\times 10^{-7}mol/L=[OH^-]\)

The value of \(K_w\) at \(25^o C\) will be :

\(K_w=[H^+]\times [OH^-]=1\times 10^{-7}\times 1\times 10^{-7}=1\times 10^{-14}\)