An atom requires 6.24 × 10−19J to remove its furthest electron in the gas phase. What is the maximum wavelength of electromagnetic radiation that will result in ionization? Report your numerical answer in units of nm. Use significant figures.
Solution:
1. Determine the frequency:
E=hv
6.24 x 10-19 J = (6.626 x 10-32 Js) x (v)
v = 9.417 x 10^14 s-1
2. Determine the wavelength:
λv = c
(λ) x (9.417 x 10^14 s-1) = 3.00 x 10^8 m/s
λ = 3.18 x 10-7 m
Wavelength (λ) = 318nm
The maximum wavelength of electromagnetic radiation that will result in ionization is 318.6 nm.
The given parameters;
The maximum wavelength of electromagnetic radiation that will result in ionization is calculated as follows;
E = hf
\(E = h\frac{c}{\lambda}\)
where;
The maximum wavelength is calculated as;
\(\lambda = \frac{hc}{E} \\\\\lambda = \frac{(6.626\times 10^{-34}) \times (3\times 10^8)}{6.24\times 10^{-19}} \\\\\lambda = 3.186 \times 10^{-7} \ m\\\\\lambda = 318.6 \times 10^{-9} \ m\\\\\lambda = 318.6 \ nm\)
Thus, the maximum wavelength of electromagnetic radiation that will result in ionization is 318.6 nm.
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