Verified Answer :

99.6 mg= .0996 g
.0996g x (1mol/125.05g) x (1 mol SO3/1 mol Na2SO2) x (6.02 x 10^22/1mol SO3) = 4.79 x 10^19 SO32- ions

Answer : The number of \(SO_3^{2-}\) ions are, \(47.57\times 10^{19}\)

Explanation : Given,

Mass of \(Na_2SO_3\) = 99.6 mg = 0.0996 g

Conversion used : (1 mg = 0.001 g)

Molar mass of \(Na_2SO_3\) = 126.05 g/mole

First we have to calculate the moles of \(Na_2SO_3\).

\(\text{Moles of }Na_2SO_3=\frac{\text{Mass of }Na_2SO_3}{\text{Molar mass of }Na_2SO_3}=\frac{0.0996g}{126.05g/mole}=7.90\times 10^{-4}moles\)

Now we have to calculate the number of \(SO_3^{2-}\).

As we know that, \(Na_2SO_3\) dissociate to give 2 moles of \(Na^+\) and 1 mole of \(SO_3^{2-}\).

From this we conclude that,

As, 1 mole contains \(6.022\times 10^{23}\) number of \(SO_3^{2-}\) ions

So, \(7.90\times 10^{-4}moles\)  mole contains \((7.90\times 10^{-4})\times (6.022\times 10^{23})=47.57\times 10^{19}\) number of \(SO_3^{2-}\) ions

Therefore, the number of \(SO_3^{2-}\) ions are, \(47.57\times 10^{19}\)