A ground state hydrogen atom absorbs a photon of light having a wavelength of 92.30 nm. It then gives off a photon having a wavelength of 1820 nm. What is the final state of the hydrogen atom?
energy provided=13.4 eV
energy released=0.7 eV
energy absorbed = 12.7eV
initial energy= -13.6eV [ground state]
final energy = -13.6+12.7 = -0.9 eV
This energy corresponds to n=4 in hydrogen atom
Answer:
n=5
Explanation:
We use the Rydberg formula to solve this problem:
1 / λ =\(R_{H}*(\frac{1}{n_{1}^{2}}-\frac{1}{n_{2}^{2}} )\)
Where λ is the wavelength of absorption/emission, RH is a constant (1.09710⁷m⁻¹), n₁ is the state of minor energy and n₂ is the state with higher energy.
1 / 92.3 10⁻⁹m = 1.09710⁷m⁻¹ \((\frac{1}{1^{2}}-\frac{1}{n_{2}^{2}} )\)
0.988 = \(1-\frac{1}{n_{2}^{2}}\)
\(\frac{1}{n_{2}^{2}}=0.012\\\)
n_{2}^{2}=83.333\
_{2}=9.12[/tex]
So after absorbing the wavelength of 92.30 nm the state of the hydrogen atom is n=9
\(1 / 1.82*10^{-6}m = 1.097*10^{7}m*(\frac{1}{n_{2}^{2}}-\frac{1}{9^{2}} )\\5.009*10^{-2}=\frac{1}{n_{2}^{2}}-\frac{1}{81}\\\frac{1}{n_{2}^{2}}=0.0377\ _{2}^{2}=26.50\ _{2}=5.14\)
So the final state of the hydrogen atom is n=5